Tetrahedron p. 5189 - 5198 (1988)
Update date:2022-07-30
Topics:
Kulkarni, Gururaj C.
Karmarkar, Sanjay N.
Kelkar, Shriniwas L.
Wadia, Murzban S.
Reactions of substituted desyl chloride 1 and 5 with phenol at room temperature in benzene results in C-alkylation.The reaction is shown to proceed through a benzylic α-acylcarbenium ion.This contention is supported by (i) the failure of this reaction with haloketones 8 and 22 and (ii) the different nature of products obtained when these haloketones were allowed to react in the presence of K2CO3.
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