GENERATION AND CYCLOADDITIONS OF HYDROXY(AND TRIMETHYLSILOXY)PHENYLETHYNYLKETENE

DOI: 10.1016/0040-4039(88)85203-1

Source and publish data:

Tetrahedron Letters p. 2765 - 2768 (1988)

Update date:2022-08-05

Topics:

Authors:

Fernandez, Mario

Pollart, Daniel J.

Moore, Harold W.

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Article abstract of DOI:10.1016/0040-4039(88)85203-1

An unusual rearragement of 5,6-dihydroxy-1,3-dimethoxy-5,6-diphenylethynyl-1,3-cyclohexadiene (1) to 7-hydroxy-1,4-dimethoxy-2-phenylethynylbicyclo<2.2.2>octadiene-8-one (2a) was observed when 1 was treated with ZnCl2 in refluxing carbon tetrachloride.The

Full text of DOI:10.1016/0040-4039(88)85203-1

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