Journal of Organic Chemistry p. 2317 - 2321 (1989)
Update date:2022-07-29
Topics:
Modi, Sandeep P.
Gardner, John O.
Milowsky, Arnold
Wierzba, Mark
Forgione, Lisa
et al.
Grignard reaction with 16-dehydropregnenolone acetate, 1, results in 1,4-addition to the enone system.Introduction of even trace amounts of oxygen before the reaction has been fully quenched results in formation of 17α-hydroperoxides as well as the expect
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