Tetrahedron Letters p. 453 - 456 (1997)
Update date:2022-07-29
Topics:
Hoshi, Masayuki
Takahata, Kimitomo
Arase, Akira
The reaction of (Z)-1-halo-1-alkenyldialkylborane (1) with tributyltin hydride (n-Bu3SnH) at 0°C or room temperature results in reductive removal of the halogen atom to afford (E)- or (Z)-1-alkenyldialkylborane whose stereochemistry depends on the dialkylboryl group and the alkenyl group of 1.
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(1997)
