Tetrahedron p. 5791 - 5808 (1988)
Update date:2022-08-04
Topics:
Kramell, R.
Schmidt, J.
Schneider, G.
Sembdner, G.
Schreiber, K.
Both racemic jasmonic acid <(+/-)-JA> and the naturally occurring (-)-enantiomer <(-)-JA> have been reacted with aliphatic, aromatic as well as acidic amino acids to form amide-linked derivatives.The diastereoisomeric products of (+/-)-jasmonic acid with S-Val, S-Leu, S-Ile, S-Phe, S-Trp, R-Val, and R-Phe could be separated by silica gel chromatography.The synthesized N-(jasmonoyl)-conjugates have been structurally characterized by MS, (1)H NMR, IR and ORD.
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