ENANTIOSELECTIVE SYNTHESIS OF THE SPIROKETAL UNIT OF MILBEMYCINS AND 22,23-DIHYDROAVERMECTINS

DOI: 10.1016/S0040-4039(00)82149-8

Source and publish data:

Tetrahedron Letters p. 3667 - 3670 (1988)

Update date:2022-09-26

Topics:

Authors:

Ferezou, J. P.

Gauchet-Prunet, J.

Julia, M.

Pancrazi, A.

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Article abstract of DOI:10.1016/S0040-4039(00)82149-8

The crystalline spiroketal sub-unit 9 has been synthesized in ten steps from the 2S,3R-diol 2 using a remote partial stereocontrol for the aldolisolation step.

Full text of DOI:10.1016/S0040-4039(00)82149-8

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