Syntheses and Tandem Diels-Alder Reactivities of 7,7-Diphenylhericene(=7-(Diphenylmethylidene)-2,3,5,6-tetramethylidenebicycloheptane) and 7-Oxahericene(=2,3,5,6-Tetramethylidenebicycloheptan-7-one)

DOI: 10.1002/hlca.19880710538

Source and publish data:

Helvetica Chimica Acta p. 1268 - 1280 (1988)

Update date:2022-07-30

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Authors:

Rubello, Albino

Vogel, Pierre

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Article abstract of DOI:10.1002/hlca.19880710538

Syntheses of 7,7-diphenyl<2.2.1>hericene (4) and 7-oxa<2.2.1>hericene (5) are presented.Rate constants k1 and k2 of the two successive Diels-Alder additions of ethylenetetracarbonitrile (TCE) to 4 and to 5 have been evaluated.At 25 deg C in toluene, the r

Full text of DOI:10.1002/hlca.19880710538

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