ALLYLIC STEREOCENTER DIRECTED ASYMMETRIC CONJUGATE ADDITION OF CUPRATES IN THE PRESENCE OF TRIMETHYLCHLOROSILANE. ENANTIOSELECTIVE SYNTHESIS OF 2-ALKYL-4-BENZYLOXYBUTANAL AND 2-ALKYL-4-OXOPENTANAL.

DOI: 10.1016/S0040-4020(01)81451-4

Source and publish data:

Tetrahedron p. 5929 - 5938 (1988)

Update date:2022-08-03

Topics:

Authors:

Cardani, Silvia

Poli, Giovanni

Scolastico, Carlo

Villa, Roberto

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)81451-4

Cuprate reagents in the presence of trimethylchlorosilane add with excellent Π-face selectivity and yield to α,β-unsaturated ketone and aldehyde bearing in γ-position a masked aldehyde represented by the C-2 of a norephedrine-derived oxazolidine.The title

Full text of DOI:10.1016/S0040-4020(01)81451-4

Products guided by the article

Product name:(2S,4S,5R)-2-((S)-3-Hydroxy-1-methyl-propyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester

Cas No:120810-97-1

R&D Labs maybe for 120810-97-1

Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China

Relevant to this article

Efficient copolymerization of ethylene with norbornene or its derIVatIVes using half-metallocene zirconium(IV) catalysts

Doi:10.1039/c6ra11501b
(2016)
Mitochondrial targeting of cyclosporin A enables selective inhibition of cyclophilin-D and enhanced cytoprotection after glucose and oxygen deprivation

Doi:10.1042/BJ20090332
(2010)
Hydroxyl-directed intermolecular ketone-olefin couplings promoted by SmI₂

Doi:10.1002/(SICI)1521-3765(19991105)5:11<3252::AID-CHEM3252>3.0.CO;2-D
(1999)
Synthesis of (±)-threo-3-[(benzyloxycarbonyl)oxy]-2-fluorotetradecanoic acid

Doi:10.1021/jo00276a050
(1989)
A new zincate-mediated rearrangement reaction of 2-(1-hydroxyalkyl)-1- alkylcyclopropanol

Doi:10.1002/chem.200901054
(2010)
Indolizines. 4. Dyes Derived from Oxoindolizinium Ions and Active Methylene Compounds

Doi:10.1021/jo00276a029
(1989)

Article Doi