ALLYLIC STEREOCENTER DIRECTED ASYMMETRIC CONJUGATE ADDITION OF CUPRATES IN THE PRESENCE OF TRIMETHYLCHLOROSILANE. ENANTIOSELECTIVE SYNTHESIS OF 2-ALKYL-4-BENZYLOXYBUTANAL AND 2-ALKYL-4-OXOPENTANAL.

DOI: 10.1016/S0040-4020(01)81451-4

Source and publish data:

Tetrahedron p. 5929 - 5938 (1988)

Update date:2022-08-03

Topics:

Authors:

Cardani, Silvia

Poli, Giovanni

Scolastico, Carlo

Villa, Roberto

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Article abstract of DOI:10.1016/S0040-4020(01)81451-4

Cuprate reagents in the presence of trimethylchlorosilane add with excellent Π-face selectivity and yield to α,β-unsaturated ketone and aldehyde bearing in γ-position a masked aldehyde represented by the C-2 of a norephedrine-derived oxazolidine.The title

Full text of DOI:10.1016/S0040-4020(01)81451-4

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