AN EFFICIENT SYNTHESIS OF 5-ARYL(or ALKYL)AMINO-4-ETHOXYCARBONYL-2-METHYLTHIO-1,3-THIAZOLES FROM DIMETHYL N-(ETHOXYCARBONYLMETHYL)IMINODITHIOCARBONATE AND ISOTHIOCYANATES.

DOI: 10.3987/COM-88-4613

Source and publish data:

Heterocycles p. 2177 - 2184 (1988)

Update date:2022-09-26

Topics:

Authors:

Alvarez-Ibarra, Carlos

Gil, Matilde

Ortiz, Paloma

Quiroga, Maria L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.3987/COM-88-4613

An efficient synthesis of perfunctionalyzed 1,3-thiazoles 2a-2b with good yields has been carried out by a cyclocondensation reaction between the α-metallated dimethyl N-(ethoxycarbonylmethyl)iminodithiocarbonate and aryl or alkylisothiocyanates.

Full text of DOI:10.3987/COM-88-4613

Products guided by the article

Product name:4-(ethoxycarbonyl)-2-(methylthio)-5-(phenylamino)thiazole

Cas No:120933-01-9

R&D Labs maybe for 120933-01-9

SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Anyang Double Circle Auxiliary CO.,LTD

Contact:0086-134 6082 4403

Address:dongfeng road, anyang city, henan province,china
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China
Advanced Biotech

Contact:+1-973-357-0577

Address:10 Taft Rd.

Relevant to this article

Gallium tri-chloride derivatives of the sterically demanding pyridines 2,6-Ar₂C₆H₃N (Ar = 2,4,6-Me₃C₆H₂ or 2,4,6-Prⁱ₃C₆H₂)

Doi:10.1016/j.poly.2009.06.011
(2010)
Highly enantioselective direct allylic alkylation of butenolides with Morita-Baylis-Hillman carbonates catalyzed by chiral squaramide-phosphine

Doi:10.1039/c5ra14667d
(2015)
Pharmaceutical-Oriented Methoxylation of Aryl C(sp ²)-H Bonds using Copper Catalysts

Doi:10.1055/s-0037-1610132
(2018)
Studies on the reaction of α-chloroformylarylhydrazine hydrochloride¹ with N-heterocyclic compounds

Doi:10.1002/jccs.200200037
(2002)
Microwave-mediated efficient protection of carbonyl compounds as 1,3-oxathiolanes in the presence of iodine under solvent free condition

Doi:10.1246/cl.2006.542
(2006)
Asymmetric synthesis of β-amino alcohols by cross-pinacol coupling of planar chiral ferrocenecarboxaldehydes with imines [2]

Doi:10.1021/ja000479v
(2000)

Article Doi