THE CARBONYL EPOXIDE REARRANGEMENT. EPOXY IMINES IN THE FORMATION OF HETEROTROPANE DERIVATIVES.

DOI: 10.1016/S0040-4039(00)80656-5

Source and publish data:

Tetrahedron Letters p. 4973 - 4976 (1988)

Update date:2022-08-05

Topics:

Authors:

Wasserman, Harry H.

Thyes, Marco

Wolff, Steven

Rusiecki, Victoria

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80656-5

The carbonyl epoxide rearrangement can be extended to δ, ε-epoxy imines.The reaction takes place by intramolecular nucleophilic displacement involving attack of the imino nitrogen on the epoxide ring.A high degree of stereospecificity is observed in this process which provides a facile route to 6-oxa-8-azabicyclo<3.2.1>octanes.

Full text of DOI:10.1016/S0040-4039(00)80656-5

Products guided by the article

Product name:5,8-dimethyl-6-oxa-8-azabicyclo<3.2.1>octane

Cas No:121179-63-3

R&D Labs maybe for 121179-63-3

Forsman Scientific(Beijing)co.,Ltd.

Contact:+86-10-64646565

Address:Rm No.1301, Building-2, No. A-13 Beiyuan Road, Chaoyang District Beijing, China, PR,
Shanghai agrotree chemical co.,ltd.

Contact:+86-21-50117563

Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China
Shanghai Sharing technologies Co., Ltd.

Contact:86-021-66787223

Address:No11, Lane 225, Jinxiang Road,Pudong district
WuHan rongfashun BioChemical co., LTD

Contact:02788866139

Address:No.95 LuoYu Road,Wuhan
Sigma-Aldrich Chemie GmbH

website:http://www.sigmaaldrich.com

Contact:800 558-9160

Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland

Relevant to this article

Design, synthesis, and evaluation of 2-methyl- and 2-amino-N-aryl-4,5- dihydrothiazolo[4,5-h]quinazolin-8-amines as ring-constrained 2-anilino-4-(thiazol-5-yl)pyrimidine cyclin-dependent kinase inhibitors

Doi:10.1021/jm901660c
(2010)
Synthesis and reactions of the optically active dialkyl diselenides from the pinane group

Doi:10.2174/157017809788489846
(2009)
Organorhodium(I) and -rhodium(III) complexes containing the ligand 1,1,1-tris((diphenylphosphino)methyl)ethane (triphos)

Doi:10.1021/om00110a011
(1989)
Selective sulfenylative desulfonylation or decarbalkoxylation of α-sulfonyl malonates with DABCO or Bu3N: Reactivity and conformational analysis

Doi:10.1080/00397910902962852
(2010)
Parallel assembly of dipolar columns composed of a stacked cyclic tri-β-peptide

Doi:10.1039/b600407e
(2006)
Iron-catalyzed regioselective hydroaryloxylation of C≡C Triple Bonds: An efficient synthesis of 2H-1-benzopyran derivatives

Doi:10.1002/adsc.200900483
(2009)

Article Doi