Tetrahedron Letters p. 4973 - 4976 (1988)
Update date:2022-08-05
Topics:
Wasserman, Harry H.
Thyes, Marco
Wolff, Steven
Rusiecki, Victoria
The carbonyl epoxide rearrangement can be extended to δ, ε-epoxy imines.The reaction takes place by intramolecular nucleophilic displacement involving attack of the imino nitrogen on the epoxide ring.A high degree of stereospecificity is observed in this process which provides a facile route to 6-oxa-8-azabicyclo<3.2.1>octanes.
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