Tetrahedron Letters p. 3457 - 3460 (1991)
Update date:2022-09-26
Topics:
Santiago, Braulio
Lopez, Carlos
Soderquist, John A.
The reactions of cis-α-epoxysilanes (1) with an excess of alkyllithium reagents were found to cleanly provide 1,2-dialkylvinylsilanes (3).A model for this reductive alkylation is advanced which explains the role of substituents in determining the product stereochemistry.
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