SYNTHESIS OF γ-LACTONES FROM ALKENES EMPLOYING p-METHOXYBENZYL CHLORIDE AS (1+)CH2-CO2(1-) EQUIVALENT

DOI: 10.1016/S0040-4039(00)88476-2

Source and publish data:

Tetrahedron Letters p. 6925 - 6926 (1988)

Update date:2022-08-04

Topics:

Authors:

Baeuml, Englbert

Tscheschlok, Kai

Pock, Rudolf

Mayr, Herbert

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Article abstract of DOI:10.1016/S0040-4039(00)88476-2

The ZnCl2 catalyzed reaction of p-methoxybenzyl chloride with alkenes yields the 1:1 addition products 3, which are converted into the γ-lactones 4 via Ru(VIII) catalyzed oxidative degradation of the aromatic ring.

Full text of DOI:10.1016/S0040-4039(00)88476-2

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Product name:1-(3-Chloro-3-methyl-hexyl)-4-methoxy-benzene

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