Synthetic Communications p. 570 - 579 (2010)
Update date:2022-08-05
Topics:
Chen, Chao
Yan, Xiaoyu
Xi, Chanjuan
Reaction of zirconacyclopentadienes with 2-bromoalkenes in the presence of CuCl afforded multisubstituted benzene derivatives. The reactions of 2-bromoacrylate and 2-bromo-3-phenylacrylaldehyde afforded penta-and hexasubstituted benzenes in good yields. The reaction of 3-bromofuran-2,5-dione with zirconacyclopentadienes gave isobenzofuran-1,3-diones in good yields. Copyright Taylor & Francis Group, LLC.
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Doi:10.1016/j.tetasy.2010.01.003
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