Advanced Synthesis and Catalysis p. 3101 - 3106 (2009)
Update date:2022-08-03
Topics:
Liang, Gang
Tong, Min-Chao
Wang, Chun-Jiang
The first catalytic endo-selective 1,3-dipolar cycloaddition of azomethine ylides and vinyl phenyl sulfone has been developed successfully. The highly efficient silver acetate (AgOAc)/TF-BiphamPhos catalytic system exhibited high reactivity, excellent diastereoselectivity (>98:2), good enantioselectivity (67-92% ee) and broad substrate scope under mild conditions.
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