Syntheses and Reactivity of Acetylide-containing Clusters of Group 1B Metals. Stepwise Syntheses of Trinuclear - and Pentanuclear - and - Clusters

DOI: 10.1039/DT9880002297

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2297 - 2300 (1988)

Update date:2022-08-03

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Authors:

Abu-Salah, Omar M.

Al-Ohaly, Abdel Razzak A.

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Article abstract of DOI:10.1039/DT9880002297

The pentanuclear cluster ^- was obtained from the reaction between <_n> and a mixture of ^- and <_n>.Its structure is described.The same cluster has been synthesized in a stepwise manner starting with ^- through the binuclear complex ^- and the trinuclear cluster ^-.The synthesis of the analogous gold-silver cluster ^- was achieved by a slightly modified method.

Full text of DOI:10.1039/DT9880002297

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