ACTION D'HALOGENOSILANES SUR LES OXYDES DE VINYL-2 FURANNE, DE STYRENE ET DE BUTENE-1. ETUDE DES REGIO ISOMERES PAR RMN-(13)C

DOI: 10.1016/0040-4039(88)85148-7

Source and publish data:

Tetrahedron Letters p. 3307 - 3310 (1988)

Update date:2022-07-29

Topics:

Authors:

Maraval, M.

Borredon, M. E.

Delmas, M.

Dubac, J.

Gaset, A.

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Article abstract of DOI:10.1016/0040-4039(88)85148-7

(13)C-NMR shows that the regiochemistry of the reaction of a halosilane Me3SiX (X=Cl, Br) on a dissymetric epoxide depends of R: RCHXCH2OSiMe3 (a, R=2-Fu, Ph) or RCHOSiMe3CH2X (b, R=Et, b>a).

Full text of DOI:10.1016/0040-4039(88)85148-7

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