Diastereoselective asymmetric induction in the thio-Claisen rearrangement over zeolites

DOI: 10.1016/S0040-4039(97)00370-5

Source and publish data:

Tetrahedron Letters p. 2413 - 2416 (1997)

Update date:2022-08-03

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Authors:

Sreekumar

Padmakumar, Raghavakaimal

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Article abstract of DOI:10.1016/S0040-4039(97)00370-5

S-Allyl γ-hydroxy ketene dithioacetals [1a-1e] underwent a rapid and diastereoselective thio-Claisen rearrangement into anti α-allyl β-hydroxy dithioesters [2a-2e] over various zeolites at room temperature in hexane is described.

Full text of DOI:10.1016/S0040-4039(97)00370-5

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