SYNTHESIS OF (Z)-PREDOMINANT α,β-UNSATURATED NITRILES FROM ENONE CYANOHYDRIN DIETHYL PHOSPHATES: APPLICATION TO THE SYNTHESIS OF (+/-)-NUCIFERAL, (+/-)-(E)-AND -(Z)-NUCIFEROL, AND (+/-)-MANICONE

DOI: 10.1039/P19880003163

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3163 - 3168 (1988)

Update date:2022-08-04

Topics: Synthesis Application

Authors:

Yoneda, Ryuji

Harusawa, Shinya

Kurihara, Takushi

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Article abstract of DOI:10.1039/P19880003163

Enone cyanohydrin diethyl phosphates reaced regio- and stereo-selectively with a variety of organocopper reagents to give γ-coupling products, (Z)-predominant alk-2-enenitriles.The methodology was applied to the synthesis of (+/-)-nuciferal, (+/-)-(E)- an

Full text of DOI:10.1039/P19880003163

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