Journal of the Chemical Society. Chemical communications p. 591 - 592 (1988)
Update date:2022-08-04
Topics:
Ohe, Kouichi
Takahashi, Hidetaka
Uemura, Sakae
Sugita, Nobuyuki
Treatment of aromatic nitro compounds with sodium borohydride in alkaline ethanol in the presence of a catalytic amount of diphenyl ditelluride at 25 deg C affords the corresponding azoxy compounds selectively in high yields, in situ generated sodium benzenetellurolate being the active species which produces the intermediate aromatic nitroso compounds.
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