Naphthalene-catalysed lithiation of 2-(chlorophenyl)-1,3-dioxolanes: Generation of formyl- and acetyl-phenyllithium equivalents [1]

DOI: 10.1016/S0040-4020(99)00092-7

Source and publish data:

Tetrahedron p. 4043 - 4050 (1999)

Update date:2022-08-05

Topics: Naphthalene Lithiation

Authors:

Huerta, Fernando F.

Gomez, Cecilia

Yus, Miguel

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Article abstract of DOI:10.1016/S0040-4020(99)00092-7

The reaction of 2-(chlorophenyl)-1,3-dioxolanes 1 with an excess of lithium powder and a catalytic amount of naphthalene (5 mol %) in the presence of different carbonyl compounds [(t)BuCHO, Et₂CO, (CH₂)₅CO, PhCOMe] as elec

Full text of DOI:10.1016/S0040-4020(99)00092-7

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Product name:2-(2-chlorophenyl)-2-methyl-1,3-dioxolane

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