
Journal of Organic Chemistry p. 5343 - 5347 (1989)
Update date:2022-08-05
Topics:
Hernandez, Rosendo
Rivera, Augusto
Suarez, Ernesto
Prange, Thierry
A new metabolite, spathulasin (1), is described as a natural product from Aeonium spathulatum.The structure of the 14-membered lactone derivative 10 was determined by X-ray crystallographic analysis.Hydrolysis of spathulasin and identification of the pentose portion as L-arabinose allowed the assignation of the absolute configuration of all centers in 1.
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