Journal of Organic Chemistry p. 2903 - 2907 (1980)
Update date:2022-09-26
Topics:
Asai, Nobuyoshi
Neckers, Douglas C.
The synthesis of UV-stable photosensitizers poly(p-(trifluorovinyl)benzophenone) and poly(p-(trifluorovinyl)acetophenone) and their use as a homogeneous and heterogeneous triplet-state energy-transfer donor are herein described.The photosensitizers are advantageous both because of the separation advantages provided by the macromolecule and the nearly diffusion-controlled energy-transfer rate of a sensitizer in solution.Poly(p-trifluorovinyl)acetophenone) is insoluble in certain solvents, thus providing the separation advantages of a heterogeneous energy-transfer donor.
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