Journal of the Chemical Society. Perkin transactions I p. 579 - 581 (1989)
Update date:2022-07-29
Topics:
Foster, Richard W. G.
Marples, Brian A.
The photolysis of α-oxo-oxetanes appears to be controlled in part by stereoelectronic factors which require coplanarity of the α-cleaved oxetane bond with the singly or doubly occupied carbon p-orbital of the n,?* carbonyl group and the zwitterionic character of the initial bond cleaved species may be important.
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Doi:10.1021/jo00284a037
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