Platinum Complexes of the Tripod-like Ligand Tris(2-diphenylphosphinoethyl)amine (tdpea). X-Ray Crystal Structure of BPh4

DOI: 10.1039/DT9900002293

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2293 - 2298 (1990)

Update date:2022-08-05

Topics:

Authors:

Ghilardi, Carlo A.

Midollini, Stefano

Moneti, Simonetta

Orlandini, Annabella

Scapacci, Giancarlo

Traversi, Aldo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9900002293

Treatment of with the tripod-like ligand tris(2-diphenylphosphinoethyl)amine, N(CH2CH2PPh2)3 (tdpea), affords the tetrahedral derivative .This species undergoes oxdative-addition reactions allowing the preparation of alkyl, hydrido, chloromethyl, and iodo five-co-ordinated species.An X-ray structure determnation for the chloromethyl derivative has been carried out.Crystal data: monoclinic, space group P2₁/n, a=34.601(9), b=17.136(5), c=10.718(3) Angstroem, β=94.56(8) deg, and Z=4.The structure has been solved by three-dimensional Patterson and Fourier syntheses and refined by least squares to a conventional R value of 0.069.

Full text of DOI:10.1039/DT9900002293

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(hydrido){tris(2-diphenylphosphino-κP-ethyl)amine-κN}platinum tetraphenylborate

Cas No:123224-15-7

R&D Labs maybe for 123224-15-7

Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
Hangzhou Maytime Bio-Tech Co.,Ltd.

website:http://www.maytime.com.cn

Contact:+86-571-88925295 88920965

Address:NO.2-1701 Ganghui Central Ningwei Street, Xiaoshan Hangzhou Zhejiang China
Tangshan Moneide Trading Co., Ltd.

Contact:+86-315-8309571

Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China

Relevant to this article

Structural modifications of anguidin and antitumor activities of its analogues

Doi:10.1021/jm00347a018
(1982)
Crystal Structure and Chemical Properties of Tris(2,6-dimethoxyphenyl)phosphine Selenide

Doi:10.1246/bcsj.69.655
(1996)
Elaborate ligand-based pharmacophore exploration and QSAR analysis guide the synthesis of novel pyridinium-based potent β-secretase inhibitory leads

Doi:10.1016/j.bmc.2010.03.043
(2010)
Molecularly imprinted mesoporous silica particles showing a rapid kinetic binding

Doi:10.1039/c003173a
(2010)
Hydrido-osmium(II), -osmium(IV) and -osmium(VI) complexes with functionalized phosphanes as ligands

Doi:10.1002/ejic.200900706
(2009)
Efficient cross-coupling of dioxazaborocanes with α-phosphate enamides

Doi:10.1002/ejoc.201402927
(2014)

Article Doi