Platinum Complexes of the Tripod-like Ligand Tris(2-diphenylphosphinoethyl)amine (tdpea). X-Ray Crystal Structure of BPh4

DOI: 10.1039/DT9900002293

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2293 - 2298 (1990)

Update date:2022-08-05

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Authors:

Ghilardi, Carlo A.

Midollini, Stefano

Moneti, Simonetta

Orlandini, Annabella

Scapacci, Giancarlo

Traversi, Aldo

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Article abstract of DOI:10.1039/DT9900002293

Treatment of with the tripod-like ligand tris(2-diphenylphosphinoethyl)amine, N(CH2CH2PPh2)3 (tdpea), affords the tetrahedral derivative .This species undergoes oxdative-addition reactions allowing the preparation of alkyl, hydrido, chloromethyl, and iodo five-co-ordinated species.An X-ray structure determnation for the chloromethyl derivative has been carried out.Crystal data: monoclinic, space group P2₁/n, a=34.601(9), b=17.136(5), c=10.718(3) Angstroem, β=94.56(8) deg, and Z=4.The structure has been solved by three-dimensional Patterson and Fourier syntheses and refined by least squares to a conventional R value of 0.069.

Full text of DOI:10.1039/DT9900002293

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