
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry p. 279 - 288 (1999)
Update date:2022-08-02
Topics:
Zhang, Yin-Han
Liu, Yun-Ping
Fan, Shao-Hua
A solid state reaction was successfully applied for the first time to synthesize complexes of lead(II) with the porphyrin derivatives meso-tetra(4-hydroxyphenyl)porphyrin, meso-tetra(4-methoxyphenyl)porphyrin and meso-tetra(4-nitrophenyl)porphyrin. The influence of the composition and structure of the porphyrin, temperature, initiator and mixing degree on the reactions was studied. IR, UV absorption and fluorescence spectra show the compositions and structures of the complexes are the same as those synthesized in solution.
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