Tetrahedron Letters p. 2633 - 2636 (1989)
Update date:2022-08-03
Topics:
Padwa, Albert
Krumpe, Keith E.
Zhi, Lin
Treatment of several ortho alkynyl substituted α-diazoacetophenone derivatives with rhodium (II) acetate results in intramolecular addition to the acetylenic pi-bond to give a transient cyclopropene which spontaneously rearranges to a vynil carbene interm
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