Journal of Organic Chemistry p. 315 - 318 (1990)
Update date:2022-07-30
Topics:
Hatzigrigoriou, Evangelia
Varvoglis, Anastasios
Bakola-Christianopoulou, Maria
The title compound is prepared and used for the direct α-((10-camphorsulfonyl)oxylation) of various ketones and carbonyl compounds with an active methylene group.Its reaction with 2-butanone and 4-methyl-2-pentanone yields predominantly the corresponding 1-sulfonyloxy derivatives.The stereoselectivity of the reaction is studied by using benzoylacetone, ethyl benzoylacetate, and propiophenone.In some reactions 10-camphorsulfonyl peroxide is formed as a byproduct.
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