Cyclisation of α,β,χ,ψ-Unsaturated Dioic Acid Esters via Tandem Conjugate Additions by using Lithium N-Benzyltrimethylsilylamide (LSA) as a Nitrogen Nucleophile and its Application to a Total Synthesis of (+/-)-Dihydronepetalactone and (+/-)-Isodihydronep

DOI: 10.1039/c39890000113

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Journal of the Chemical Society. Chemical communications p. 113 - 114 (1989)

Update date:2022-08-04

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Authors:

Uyehara, Tadao

Shida, Naomi

Yamamoto, Yoshinori

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Article abstract of DOI:10.1039/c39890000113

A stereoselective total synthesis of (+/-)-dihydronepetalactone and (+/-)-isodihydronepetalactone has been accomplished by utilising a novel cyclisation procedure; a reaction of octadiene-2,6-dioic acid esters with lithium N-benzyltrimethylsilylamide (LSA

Full text of DOI:10.1039/c39890000113

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