Tetrahedron Letters p. 1543 - 1546 (1989)
Update date:2022-08-05
Topics: Aldehydes Allylation Asymmetric Palladium-Catalyzed Enamines (S)-proline
Hiroi, Kunio
Abe, Jun
Suya, Kyoko
Sato, Shuko
Treatment of chiral enamine 3, derived from (S)-proline allyl ester (1) and 2-phenylpropionaldehyde (2), with tetrakis(triphenylphosphine)-palladium provided (R)-(-)-2-methyl-2-phenyl-4-pentenylaldehyde (5) with high enantiomeric excess.The mechanism for
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