REACTION OF GMELINOL WITH TRIETHYLSILANE AND BF3-ETHERATE - REARRANGEMENT OF THE 2,6-DIARYL-3,7-DIOXABICYCLOOCTANE SKELETON

DOI: 10.1016/S0040-4020(01)81024-3

Source and publish data:

Tetrahedron p. 3451 - 3462 (1989)

Update date:2022-09-26

Topics:

Authors:

Pelter, Andrew

Ward, Robert S.

Venkateswarlu, Reveru

Kamakshi, C.

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Article abstract of DOI:10.1016/S0040-4020(01)81024-3

Reaction of gmelinol 1 with triethylsilane and BF3-etherate gave two products, the major product 2 being an isomer of cycloolivil dimethyl ether, formed by reductive rearrangement of the 2,6-diaryl-3,7-dioxabicyclo<3.3.0>octane skeleton.The minor product

Full text of DOI:10.1016/S0040-4020(01)81024-3

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