Chemistry of Heterocyclic Compounds p. 136 - 142 (1989)
Update date:2022-09-26
Topics:
Kuznetsov, M. A.
Semenovskii, V. V
Belov, V. N.
Gindin, V. A
The addition of phthalimidonitrene with phenylbutenynes proceeds exclusively at the double bond and leads to derivatives of 1-phthalimido-2-ethynylaziridine in high yield.The observed chemoselectivity of this reaction is attributed to the antiaromatic transition state in the case of the addition of phthalimidonitrene to the triple bond.
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