ALKYLATIVE EPOXIDE REARRANGEMENT. APPLICATION TO STEREOSELECTIVE SYNTHESIS OF CHIRAL PHEROMONE EPOXIDES.

DOI: 10.1016/S0040-4039(00)82468-5

Source and publish data:

Tetrahedron Letters p. 865 - 868 (1988)

Update date:2022-08-02

Topics: Characterization Stereochemistry Isolation and Purification

Authors:

Bell, Thomas W.

Claccio, James A.

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Article abstract of DOI:10.1016/S0040-4039(00)82468-5

An approach is described for the stereospecific conversion of threo and erythro 1,2-epoxy-3-alkanol tosylates to cis and trans internal epoxides, respectively.The method is illustrated by the synthesis of chiral epoxides, including insect pheromones.

Full text of DOI:10.1016/S0040-4039(00)82468-5

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