Eight-membered palladacycles derived from the insertion of olefins into the Pd-C bond of ortho-palladated pharmaceuticals phenethylamine and phentermine. Synthesis of stable heck-type intermediates containing accessible β-hydrogens and its use in the synt

DOI: 10.1021/om100738z

Source and publish data:

Organometallics p. 4320 - 4338 (2010)

Update date:2022-08-05

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Authors:

Vicente, Jose

Saura-Llamas, Isabel

Garcia-Lopez, Jose-Antonio

Bautista, Delia

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Article abstract of DOI:10.1021/om100738z

The ortho-metalated complexes derived from phenethylamine and phentermine, [Pd(C,N-C₆H₄CH₂CR₂NH ₂-2)(μ-X)]₂ (R = H, X = Br (A); R = Me, X = Cl (B)), react with olefins giving (1) the produc

Full text of DOI:10.1021/om100738z

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