THE LITHIATION AND ALKYLATION OF 4-(2'-ALKENESULPHINYL)-MORPHOLINES, A SIMPLE ROUTE TO SUBSTITUTED ALLYLIC SULPHINAMIDES

Article abstract of DOI:10.1016/S0040-4039(00)99625-4

By the reaction with 4-morpholinesulphenyl chloride carried out in the presence of trimethylamine, several substituted allylic alcohols have been converted into the corresponding allylic sulphinamides 2.As a complementary method, the new lithio-derivative