SYNTHESIS OF PROPELLANES BY "EXOCYCLIC" TRANSANNULAR CYCLOADDITION OF OLEFINIC METHYLENECYCLOPROPANES

DOI: 10.1016/S0040-4020(01)80134-4

Source and publish data:

Tetrahedron p. 3081 - 3088 (1989)

Update date:2022-08-02

Topics:

Authors:

Yamago, Shigeru

Nakamura, Eiichi

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Article abstract of DOI:10.1016/S0040-4020(01)80134-4

Olefinic methylenecyclopropanes undergo quantitative transannular ring closure under Group 10 metal catalysis to give <3.3.3>propellanes through cycloaddition of trimethylenemethane-like intermediate.

Full text of DOI:10.1016/S0040-4020(01)80134-4

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