Palladium-Catalyzed Chemoselective Negishi Cross-Coupling of Bis[(pinacolato)boryl]methylzinc Halides with Aryl (Pseudo)Halides

DOI: 10.1021/acs.orglett.9b02050

Source and publish data:

Organic Letters p. 5912 - 5916 (2019)

Update date:2022-07-30

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Authors:

Lee, Hyojae

Lee, Yeosan

Cho, Seung Hwan

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Article abstract of DOI:10.1021/acs.orglett.9b02050

We describe a palladium-catalyzed chemoselective Negishi cross-coupling of a bis[(pinacolato)boryl]methylzinc halide with aryl (pseudo)halides. This reaction affords an array of benzylic 1,1-diboronate esters, which can serve as useful synthetic handles f

Full text of DOI:10.1021/acs.orglett.9b02050

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