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Sodium Erythorbate
Cas No: 6381-77-7
No Data 1 Metric Ton 200 Metric Ton/Day EAST CHEMSOURCES LIMITED Contact Supplier
Sodium Erythorbate
Cas No: 6381-77-7
No Data 2 Metric Ton 20 Metric Ton/Day QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED Contact Supplier
D-sodium erythorbate 6381-77-7 food additive
Cas No: 6381-77-7
USD $ 0.1-0.1 / Kilogram 10 Kilogram 1000 Metric Metric Ton/Year Nanjing FNAT Chemical Co.,Ltd. Contact Supplier
Sodium Erythorbate
Cas No: 6381-77-7
USD $ 3.0-5.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Day Henan Techway Chemical Co.,Ltd. Contact Supplier
sodium Erythorbate
Cas No: 6381-77-7
No Data 5 Metric Ton 10,000 Metric Ton/Year Hebei Lead Bio-Chemicals Co., Ltd. Contact Supplier
Sodium erythorbate
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No Data No Data No Data Shanghai Rich Chemicals Co., Ltd Contact Supplier
Sodium erythorbate
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No Data No Data No Data Shang Hai Grade Biochemical Co,. Limited Contact Supplier
Sodium erythorbate Manufacturer/High quality/Best price/In stock
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USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
Best quality and well selling Sodium erythorbate
Cas No: 6381-77-7
USD $ 1.0-1.0 / Kilogram 1 Kilogram 10 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier
CAS: 6381-77-7 Sodium erythorbate
Cas No: 6381-77-7
No Data 1 Kilogram 100 Kilogram/Month Kono Chem Co.,Ltd Contact Supplier

6381-77-7 Usage

Uses

It is antioxidant and antiseptic.
Sodium Isoascorbate is a water-soluble antioxidant which is widely used in China and abroad. Its antioxidant property is significantly stronger than vitamin C. Its price is cheap as well. China provides that it can be used for all types of canned, jam and frozen fish with the maximum usage amount of 1.0g/kg; It can be used for meat with the maximum usage amount being 0.5g/kg (to ascorbic acid dollars); can be used for wine and fruit juice drinks with the largest usage amount being 0.15g/kg; can also be used for beer with the maximum usage amount being 0.04g/kg.
For food antioxidants, preservatives and coloring agent

Toxicity

ADI is not subject to any special provision (FAO/WHO, 2001).
LD50} 15.3 g/kg (mouse, orally).

Fire Hazard

Flash point data for Sodium erythorbate are not available; however, Sodium erythorbate is probably combustible.

Content analysis

0.400 g of the sample pre-dried in a vacuum desiccator (sulfuric acid) for 24 hours was dissolved in a mixed solution consisting of 100 ml of de-carbonated water and 25 ml of dilute sulfuric acid solution (TS-241). Add a few drops of starch solution (TS-235) and immediately titrate with 0.1mol/L iodine solution titration. Each mL of 0.1 mol/L iodine solution was equivalent to 10.807 mg of sodium erythorbate (C6H7O6Na? H2O).

Preparation

It is produced through using D-glucose fermentation of Pseudomonas fluorescens Kl005 or Arthrobacter globiformis K1022 to produce 2-keto-D-gluconic acid (or calcium salt), followed by being esterified, transformed and refined. The composition of the fermentation medium is: glucose: 18; yeast extract 0.3; K2HPO4 • 3H2O: 0.05; KH2PO4: 0.05; MgSO4 • 7H2O: 0.025,;CaCO:34.5. The fermentation temperature is controlled at 30~35 ℃, the fermentation period is 30h, and the fermentation conversion ratio (%) is 79.9%. The fermentation broth is supplemented with sulfate and activated carbon for acidification and decoloring, followed by pressurized filtrate to obtain the clean liquid with a yield of 96.6%.
The purified fermentation broth was concentrated by decompression, and methanol and sulfuric acid were added for refluxed esterification of 5h, followed by frozen and centrifuged filtering to obtain methyl ester with a yield of 82.1%. The methyl ester was transformed with basic methanol solution under refluxing conditions, and the product was further frozen and crystallized to dryness to obtain the crude product of D-isoascorbic acid. The conversion yield was 87.3%, and it was dissolved in hot water and decolorized with activated carbon. The filtrate is pressurized filtrated and the supernatant liquid is frozen, crystallized, centrifugalized, washed and vacuum dried to obtain finished product.
The mother liquid is recovered and the yield is 88.0%.

General Description

Almost odorless fluffy, white to off-white crystalline powder. Used as an antioxidant and preservative.

Usage limit

GB 2760-2001 (g/kg): beer 0.04; wine, fruit and vegetable juice drinks, 0.15. Canned fruits and vegetables, canned meat, jam, frozen fish, 1.0 (all based on ascorbic acid).
FAO/WHO (1984): luncheon meat, boiled forelegs, cooked ham, cooked minced meat, 500mg/kg (single usage amount or combined amount with ascorbic acid, ascorbic acid and its salts in ascorbic acid).

Chemical properties

It appears as white to yellow-white crystalline powder or granules. It is almost odorless, slightly salty. In the dry state, it is quite stable in the air. However in solution, it will deteriorate in the presence of air, trace metals, heat and light. The melting point is above 200 ℃ (decomposition). It is soluble in water (17g/100m1) but almost insoluble in ethanol. The pH of the 2% aqueous solution was 5.5 to 8.0.

Reactivity Profile

Sodium erythorbate may be sensitive to prolonged exposure to light. Incompatible with strong oxidizing agents .

Air & Water Reactions

Water soluble.

Identification test

Solubility: it is easily soluble in water; extremely difficult to dissolve in ethanol. It can be measured according to the OT-42 method.
Take 2 ml of 2.0% sample solution; add 2 mL of water, 0.1 g sodium bicarbonate and 0.02 g of ferrous sulfate. Stand after shaking. At this time, it should exhibit dark purple color while addition of 5 mL of dilute sulfuric acid test solution (TS-241) will make the color disappeared.
The burning residue of the sample was dissolved by the water and subject to (TS-2) acidification, and if necessary, subject to filtration. Addition of uranyl zinc acetate test solution (TS-253) should produce yellow crystalline precipitate.
The aqueous solution of the sample allows the discoloration of the 2, 6-dichloroindophenol test solution (TS-84).

Chemical Properties

WHITE CRYSTALLINE POWDER

Standard for Allowable Maximum Residue and Maximal amount of Foo

Name of additive Food allowed to use it as additives Function of additives Maximal allowable usage (g/kg)
Sodium Isoascorbate Eight-treasure porridge Anti-oxidants 1.0
Sodium Isoascorbate Soy sauce, vinegar, sauce, liquid compound seasoning Anti-oxidants 1.0
Sodium Isoascorbate Tea and coffee drinks Anti-oxidants 0.5
InChI:InChI=1/C6H7O6.Na/c7-1-2(8)5-3(9)4(10)6(11)12-5;/h2,5,8-10H,1H2;/q-1;+1/t2-,5-;/m1./s1

6381-77-7 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (I0232)  Sodium Isoascorbate Monohydrate  >98.0%(T) 6381-77-7 500g 450.00CNY Detail
TCI America (I0232)  Sodium Isoascorbate Monohydrate  >98.0%(T) 6381-77-7 25g 110.00CNY Detail

6381-77-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Sodium erythorbate

1.2 Other means of identification

Product number -
Other names Penite

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6381-77-7 SDS

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