The in Situ Activation of Thioglycosides with Bromine: An Improved Glycosylation Method

DOI: 10.1021/jo00296a055

Source and publish data:

Journal of Organic Chemistry p. 2860 - 2863 (1990)

Update date:2022-08-05

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Authors:

Kihlberg, Jan O.

Leigh, David A.

Bundle, David R.

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Article abstract of DOI:10.1021/jo00296a055

A one-step conversion of thioglycosides into 1,2-trans- or 1,2-cis-O-glycosides was accomplished, in situ, by treatment with bromine in the presence of a glycosyl acceptor and a promoter such as silver triflate or mercuric cyanide.This mild "one-pot" proc

Full text of DOI:10.1021/jo00296a055

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