Tetrahedron Letters p. 4203 - 4206 (1989)
Update date:2022-09-26
Topics:
Bunnelle, William H.
Shevlin, Charles G.
The reduction of α-aminonitriles with sodium proceeds via an α-aminoradical, which can be engaged in intramolecular cyclization.Reduction does not involve prior dissociation of cyanide to form an iminium species.
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Doi:10.1002/anie.201002637
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