Carbon-Carbon Bond Formation by Reaction of an Alkyne with Ruthenium(II),Complexes. Crystal Structure of 3-Ph2P-CH(CPh=CH)C(t-Bu)=O)(p-cymene)>PF6

DOI: 10.1039/c39890001035

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1035 - 1037 (1989)

Update date:2022-07-29

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Authors:

Guilbert, Benedicte

Demerseman, Bernard

Dixneuf, Pierre H.

Mealli, Carlo

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Article abstract of DOI:10.1039/c39890001035

2-Ph2PCR=C(R')O)(η⁶-arene)> complexes, prepared from α-diphenylphosphinoketones, react with phenylacetylene in the presence of AgBF4 or AgPF6 and gave regioselective carbon-carbon bond formation involving the α-phosphino carbo

Full text of DOI:10.1039/c39890001035

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Product name:RuCl₂(C₆H₄(CH₃)(CH(CH₃)2))P(C₆H₅)2CH₂COC(CH₃)3

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