Photochemical carbon-silicon bond forming reaction on electron-deficient alkenes by disilanes and polysilanes via photoinduced electron transfer

DOI: 10.1016/0022-328X(94)80103-7

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Journal of Organometallic Chemistry p. 35 - 44 (1994)

Update date:2022-07-29

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Authors:

Mizuno, Kazuhiko

Nakanishi, Kazuhisa

Chosa, Jun-ichi

Otsuji, Yoshio

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Article abstract of DOI:10.1016/0022-328X(94)80103-7

The phenanthrene-sensitized photoreaction of electron-deficient alkenes with disilanes in acetonitrile gave silylated alkanes in high yields.The photosilylation occurred in a highly regioselective manner at the position β to the electron-withdrawing group

Full text of DOI:10.1016/0022-328X(94)80103-7

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