Photochemical carbon-silicon bond forming reaction on electron-deficient alkenes by disilanes and polysilanes via photoinduced electron transfer

DOI: 10.1016/0022-328X(94)80103-7

Source and publish data:

Journal of Organometallic Chemistry p. 35 - 44 (1994)

Update date:2022-07-29

Topics:

Authors:

Mizuno, Kazuhiko

Nakanishi, Kazuhisa

Chosa, Jun-ichi

Otsuji, Yoshio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)80103-7

The phenanthrene-sensitized photoreaction of electron-deficient alkenes with disilanes in acetonitrile gave silylated alkanes in high yields.The photosilylation occurred in a highly regioselective manner at the position β to the electron-withdrawing group

Full text of DOI:10.1016/0022-328X(94)80103-7

Products guided by the article

Product name:2-[(4-Chloro-phenyl)-trimethylsilanyl-methyl]-malonic acid dimethyl ester

Cas No:126181-88-2

R&D Labs maybe for 126181-88-2

Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
LinHai Cina Chemical Co., LTD.

Contact:0576-85580989

Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.

Contact:+86-576-87501888 / 87501988

Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China

Relevant to this article

Synthesis of dysideaproline e using organocatalysis

Doi:10.1039/c0ob00617c
(2011)
Synthesis and solution properties of a novel thermosensitive poly(benzyl ether) dendron with oligoethyleneoxy chains at the periphery

Doi:10.1246/cl.2010.1177
(2010)
Synthesis of a novel ester of hydroxytyrosol and α-lipoic acid exhibiting an antiproliferative effect on human colon cancer HT-29 cells

Doi:10.1016/j.ejmech.2010.10.028
(2011)
First study of syntheses and reactivity of Grignard compounds in the diazine series. Diazines. Part 27

Doi:10.1016/S0040-4020(99)00948-5
(2000)
Self-regeneration of a silylium ion catalyst in carbonyl reduction

Doi:10.1039/c0cc02139c
(2011)
Toward an asymmetric synthesis of the dimeric pyranonaphthoquinone antibiotic crisamicin A

Doi:10.1021/jo501344c
(2014)

Article Doi