STABILIZING EFFECT OF TRIALKYLSILYL GROUP ON CARBON RADICAL: RADICAL INDUCED RING OPENING OF 1-TRIALKYLSILYL-2-VINYLCYCLOPROPANES

DOI: 10.1016/S0040-4039(00)99375-4

Source and publish data:

Tetrahedron Letters p. 4413 - 4416 (1989)

Update date:2022-08-05

Topics:

Authors:

Miura, Katsukiyo

Oshima, Koichiro

Utimoto, Kiitiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)99375-4

1-Trialkylsilyl-2-vinylcyclopropane or 3-methyl-1-trialkylsilyl-2-vinylcyclopropane provided the corresponding homoallylic silane exclusively upon treatment with PhSh, Ph3SnH, or C6F13I.On the other hand, 3-phenyl-1-trimethylsilyl-2-vinylcyclopropane or 3

Full text of DOI:10.1016/S0040-4039(00)99375-4

Products guided by the article

Product name:(E)-7-Phenylthio-4-trimethylsilyl-5-hepten-2-one

Cas No:126361-97-5

R&D Labs maybe for 126361-97-5

SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Changde Yungang Biotechnology Co., Ltd

website:http://www.cdyg.com

Contact:+86-736-7391178

Address:Qiaonan Industrial Park, Changde City, Hunan Province
Oren Hydrocarbons (Qingdao) Co., Ltd.

Contact:+86-532-68607667-801

Address:Room 3 # 302, No.9 Qingyun Road, Qingdao, China
guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
changsha chenjin chemical technology co.,LtD(expird)

Contact:86-731-84451263

Address:Room 201/217-218, 101 Jingyuan Electronic Technology Co.,Ltd. Testing Center, No.69, Lufeng Road, High-tech Development Zone, Changsha, China

Relevant to this article

Mechanism insights into an unexpected isomerisation reaction observed during conversion of N-benzyl piperazinones to corresponding N-benzyl thio-piperazinones

Doi:10.1016/j.tetlet.2010.11.096
(2011)
Dimetalated crown ether schiff base palladacycles. Influence of the carbon chain length on the coordination mode of bidentate phosphines. Crystal and molecular structure of the novel complex [Pd₂{1,4-[C(H)=N{9,10- (C₈H₁₆O<

Doi:10.1021/om100833w
(2011)
Reassignment of the structures of condensation products of α-keto α′-formylarylhydrazones with ethyl cyanoacetate: A novel route to ethyl 5-arylazo-2-hydroxynicotinates

Doi:10.1016/j.tetlet.2010.10.127
(2011)
Chiral phosphine-squaramides as enantioselective catalysts for the intramolecular Morita-Baylis-Hillman reaction

Doi:10.1039/c0cc03187a
(2011)
Synthesis and Structure-Activity Relationships of 6-Substituted 2',3'-Dideoxypurine Nucleosides as Potential Anti-Human Immunodeficiency Virus Agents

Doi:10.1021/jm00168a006
(1990)
Discovery of isoindoline and tetrahydroisoquinoline derivatives as potent, selective PPARδ agonists

Doi:10.1016/j.bmcl.2010.10.117
(2011)

Article Doi