STABILIZING EFFECT OF TRIALKYLSILYL GROUP ON CARBON RADICAL: RADICAL INDUCED RING OPENING OF 1-TRIALKYLSILYL-2-VINYLCYCLOPROPANES

DOI: 10.1016/S0040-4039(00)99375-4

Source and publish data:

Tetrahedron Letters p. 4413 - 4416 (1989)

Update date:2022-08-05

Topics:

Authors:

Miura, Katsukiyo

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)99375-4

1-Trialkylsilyl-2-vinylcyclopropane or 3-methyl-1-trialkylsilyl-2-vinylcyclopropane provided the corresponding homoallylic silane exclusively upon treatment with PhSh, Ph3SnH, or C6F13I.On the other hand, 3-phenyl-1-trimethylsilyl-2-vinylcyclopropane or 3

Full text of DOI:10.1016/S0040-4039(00)99375-4

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