Chiral N-heterocyclic carbene-copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides: Steric and electronic effects on γ-selectivity

DOI: 10.1021/jo102386s

Source and publish data:

Journal of Organic Chemistry p. 1398 - 1408 (2011)

Update date:2022-07-29

Topics:

Authors:

Selim, Khalid B.

Nakanishi, Hirotsugu

Matsumoto, Yasumasa

Yamamoto, Yasutomo

Yamada, Ken-Ichi

Tomioka, Kiyoshi

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Article abstract of DOI:10.1021/jo102386s

Chiral N-heterocyclic carbene ligands were electronically and sterically tuned to improve γ-selectivity in copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides with several aryl Grignard reagents. High γ-selectivity was realized

Full text of DOI:10.1021/jo102386s

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