Synthesis of Ambrox from communic acids

DOI: 10.1016/S0040-4020(01)87963-1

Source and publish data:

Tetrahedron p. 6251 - 6262 (1993)

Update date:2022-07-31

Topics:

Authors:

Barrero, Alejandro F.

Altarejos, Joaquin

Alvarez-Manzaneda, Enrique J.

Ramos, Jose M.

Salido, Sofia

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Article abstract of DOI:10.1016/S0040-4020(01)87963-1

Two routes for preparing Ambrox (1) from the methyl esters of trans-communic acid (2b) and/or cis-communic acid (3b), via selective degradation of their side chains, stereoselective formation of the tetrahydrofurane ring, and reduction of the axial methoxycarbonyl group, are described.

Full text of DOI:10.1016/S0040-4020(01)87963-1

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