Resonance raman spectra of reaction intermediates in the oxidation process of ruthenium(II) and iron(II) porphyrins

DOI: 10.1021/ja00165a005

Source and publish data:

Journal of the American Chemical Society p. 3289 - 3297 (1990)

Update date:2022-08-04

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Authors:

Paeng Paeng

Nakamoto

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Article abstract of DOI:10.1021/ja00165a005

The dioxo ruthenium porphyrins, RuP(O)₂ (P = TPP and TMP), were prepared by the oxidation of RuP(CO) with m-chloroperoxybenzoic acid (m-CPBA). The resonance Raman and IR spectra of RuP(O)₂ were measured and their O=Ru=O vibrations in

Full text of DOI:10.1021/ja00165a005

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