Difunctionalization of primary aromatic amines with ethylene; synthesis of μ-arylnitrilobis(ethane-2,1-diyl)dimercury(II) complexes. Crystal structure of 2,4,6-Me3C6H2N(CH2CH2HgCl)2

DOI: 10.1016/0022-328X(89)85095-8

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1989)

Update date:2022-07-30

Topics:

Authors:

Deacon, G. B.

Gatehouse, B. M.

Guddat, L. W.

Ney, S. C.

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Article abstract of DOI:10.1016/0022-328X(89)85095-8

Reaction of primary aromatic amines, mercuric acetate, and ethylene in tetrahydrofuran under pressure (ca. 40 atm.) yields the organomercurials ArN(CH2CH2HgOAc)2 (Ar=Ph, 2-ClC6H4, 3-ClC6H4, or 4-ClC6H4) or, after treatment of the crude products with sodiu

Full text of DOI:10.1016/0022-328X(89)85095-8

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