Difunctionalization of primary aromatic amines with ethylene; synthesis of μ-arylnitrilobis(ethane-2,1-diyl)dimercury(II) complexes. Crystal structure of 2,4,6-Me3C6H2N(CH2CH2HgCl)2

DOI: 10.1016/0022-328X(89)85095-8

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1989)

Update date:2022-07-30

Topics:

Authors:

Deacon, G. B.

Gatehouse, B. M.

Guddat, L. W.

Ney, S. C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(89)85095-8

Reaction of primary aromatic amines, mercuric acetate, and ethylene in tetrahydrofuran under pressure (ca. 40 atm.) yields the organomercurials ArN(CH2CH2HgOAc)2 (Ar=Ph, 2-ClC6H4, 3-ClC6H4, or 4-ClC6H4) or, after treatment of the crude products with sodiu

Full text of DOI:10.1016/0022-328X(89)85095-8

Products guided by the article

Product name:(4-MeOC₆H₄)nitrilobis(ethane-2,1-diyl)bis(chloromercury(II))

Cas No:126685-68-5

R&D Labs maybe for 126685-68-5

Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Shanghai Science Peptide Biological Technology Co.,ltd

website:http://www.scipeptide.com

Contact:+86-21-51099675

Address:No.8 Changyang Rd
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd

Contact:+86-0517-87036900

Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING

Relevant to this article

Annulation of imidazolines with bis-electrophiles: Synthesis of imidazo[1,2-a]pyridines

Doi:10.1016/S0040-4020(98)00312-3
(1998)
Anionic N-heterocyclic carbenes with N,N′-Bis(fluoroaryl) and N,N′-bis(perfluoroaryl) substituents

Doi:10.1002/chem.201001698
(2010)
Self-condensation of β-(isoxazol-5-yl) enamines under treatment with acetyl chloride and acids. Synthesis of novel 1,3-diisoxazolyl-1,3-dieneamines and 1,3,5-triisoxazolyl benzenes

Doi:10.1016/j.tet.2014.04.015
(2014)
General and highly α-regioselective zinc-mediated prenylation of aldehydes and ketones

Doi:10.1021/jo102516a
(2011)
Convergent total synthesis of (+)-TMC-151C by a vinylogous mukaiyama aldol reaction and ring-closing metathesis

Doi:10.1002/anie.201006230
(2011)
Synthesis of HCV replicase inhibitors: Base-catalyzed synthesis of protected α-hydrazino esters and selective aerobic oxidation with catalytic Pt/Bi/C for synthesis of imidazole-4,5-dicarbaldehyde

Doi:10.1021/jo4014595
(2013)

Article Doi