Bimolecular Cycloaddition Reactions of Isomuenchnones Derived from the Rhodium(II) Catalyzed Cyclization of Diazo Pyrrolidinones

DOI: 10.1016/S0040-4020(01)86338-9

Source and publish data:

Tetrahedron p. 2589 - 2600 (1993)

Update date:2022-09-26

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Authors:

Padwa, Albert

Hertzog, Donald L.

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Article abstract of DOI:10.1016/S0040-4020(01)86338-9

Treatment of diazo substituted pyrrolidinones with a catalytic amount of rhodium(II) acetate in refluxing benzene results first in the formation of a rhodium carbenoid which then cyclizes onto the neighboring carbonyl oxygen to produce an isomuenchnone ri

Full text of DOI:10.1016/S0040-4020(01)86338-9

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