Tetrahedron Letters p. 5253 - 5256 (1989)
Update date:2022-09-26
Topics:
Meier, Herbert
Wengenroth, Horst
Lauer, Wolfgang
Krause, Volker
Increasing steric hindrance in β-keto carboxylic acids leads to an increasing kinetic stability towards decarboxylation, till systems are reached wich are completely stable at room temperature.Simultaneously the tautomeric equilibrium is changed in favour of the (Z)-enol, and finally in favour of the (E)-configurated enol.
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