Angewandte Chemie - International Edition p. 1131 - 1134 (2011)
Update date:2022-08-02
Topics:
Wu, Fanghui
Green, Michael E.
Floreancig, Paul E.
A ten-step program: The potent cytotoxin pederin and several analogues have been prepared through an efficient route that proceeds in ten steps (longest linear sequence) from isobutyraldehyde. The key transformation is a multicomponent N-acylaminal construction (see scheme) that allows for late-stage fragment coupling and diversification.
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