NUCLEOPHILIC ATTACK ON 2-(4-OXOALKYL)-2-IMIDAZOLINES: A NOVEL ROUTE TO TETRAHYDROPYRIDINES AND PIPERIDINES

DOI: 10.1016/S0040-4039(01)93788-8

Source and publish data:

Tetrahedron Letters p. 5365 - 5368 (1989)

Update date:2022-08-05

Topics:

Authors:

Jones, Raymond C.F.

Hirst, Simon C.

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Article abstract of DOI:10.1016/S0040-4039(01)93788-8

2-(1-Ethoxycarbonyl-4-oxoalkyl)-2-imidazolines add organometallic carbon nucleophiles to produce new lactones,whereas hydrogenation affords 1,4,5,6-tetrahydropyridines and piperidines via a novel reductive cyclisation-cleavage pathway.

Full text of DOI:10.1016/S0040-4039(01)93788-8

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